Crystal structure of 1,5-di(pyridin-2-yl)-3-(pyridin-4-yl)- pentane-1,5-dione, C20H17N3O2

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3-(4-Hy­droxy­phen­yl)-1,5-bis­(pyridin-2-yl)pentane-1,5-dione

In the title mol-ecule, C21H18N2O3, the pyridine rings make a dihedral angle of 13.1 (1)°. The phenyl ring is approximately perpendicular to both of them, forming dihedral angles of 87.4 (1)and 81.9 (1)°. In the crystal, pairs of O-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric dimers. Additional C-H⋯O, π-π [centroid-centroid distance = 3.971 (2) Å] and C-H⋯π inter-actions consolid...

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In the title compound C18H20N2O2, the morpholine ring adopts a chair conformation with the exocyclic N-C bond in an equatorial orientation. The N atom of the morpholine ring and the C atom of the carbonyl group are in an anti conformation about the central C-C bond [torsion angle = -162.92 (11)°] and the dihedral angle between the planes of the benzene ring and the pyridine ring is 83.30 (5)°. ...

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Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC 4](pentane-2,4-dionato-κ2 O,O′)platinum(II)

The asymmetric unit of the title compound, [Pt(C10H5F2N2)(C5H7O2)], comprises one Pt(II) atom, one 2,6-di-fluoro-2,3-bi-pyridine ligand and one acetyl-acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di-fluoro-3-(pyridin-2-yl)pyridin-4-yl ligand and O,O'-chelated by the pentane-2,4-dionate ligand. The two pyridine rings of th...

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In the title racemic compound, C12H10ClNO, the dihedral angle between the benzene and pyridine rings is 74.34 (6)°. In the crystal, the mol-ecules are linked by O-H⋯N hydrogen bonds, forming zigzag C(5) [001] chains in which alternating R- and S-configuration mol-ecules are related by c-glide symmetry. In addition, inversion-related pairs of mol-ecules are linked into dimers by pairs of weak C-...

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ژورنال

عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures

سال: 2010

ISSN: 2197-4578,1433-7266

DOI: 10.1524/ncrs.2010.0349